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li-ion battery materials
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Anode MaterialsBattery AdditivesCathode MaterialsElectrolytes
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Structure-Guided Intercalation
1969 - 1998
During the Li-ion era spanning 1969 to 1998, the field coalesced around structure-guided intercalation chemistry as the dominant paradigm. In situ and structure-focused studies linked phase transitions, order–disorder phenomena, and lattice responses to lithium content in layered oxide cathodes such as lithium cobalt oxide and lithium nickel oxide, as well as spinel manganese oxides. Spinel LiMn2O4 and related compounds emerged as a testbed for defect engineering and oxygen stoichiometry control to optimize cycling and capacity, while end-member studies of Li x CoO2 mapped voltage landscapes and structural evolution at high lithiation/delithiation. Intercalation-based design also began to foreground electrolyte and interface effects, including rocking-chair configurations and surface chemistry, which govern cycle life and coulombic efficiency in practical cells.
• Structural evolution and phase transitions during lithiation/delithiation in oxide cathodes revealed by in situ and structure-focused studies, highlighting order/disorder transitions and lattice responses across lithium cobalt oxide, lithium nickel oxide, and spinel manganese oxides. Evidence from in situ X-ray diffraction and related analyses shows how composition and lithium content steer phase stability [10], [14], [11], [3].
• Spinel lithium manganese oxide family emerges as a versatile cathode class: synthesis routes, defect spinels, and careful control of oxygen stoichiometry and composition to optimize cycling performance and capacity, as demonstrated by multiple studies on LiMn2O4 and related phases [3], [5], [6], [16], [13].
• Pursuit of high-energy oxide cathodes and end-members, illustrating high-voltage operation and phase behavior in lithium intercalation systems (e.g., lithium cobalt oxide family, lithium nickel oxide) and identification of end-member states in Li x CoO2; these works map the voltage landscape and structural evolution under high lithiation/delithiation voltages [2], [10], [11], [19], [12].
• Intercalation-based design with emphasis on electrolytes and interfaces, including rocking-chair configurations and surface-chemistry-driven performance of lithium-carbon intercalation anodes, highlighting how electrode–electrolyte interfaces govern cycle life and coulombic efficiency in practical cells [4], [18], [1].
Popular Keywords
Nanostructured Lithium Storage Materials
1999 - 2005
Nanostructured Electrode Architectures
2006 - 2012
Interfacial Engineering for Lithium-Ion
2013 - 2018
Solid Electrolyte Interphase
2019 - 2025